Brochantite

A secondary copper sulphate mineral which occurs in the oxidised zones of copper bearing orebodies.

Can form some exceptional micro mineral specimens.

Information about Brochantite

Brochantite is one of the most widely distributed secondary copper minerals, forming brilliant emerald-green to dark green prismatic crystals and acicular aggregates in the oxidised zones of copper ore deposits worldwide – and also, less obviously, as a common corrosion product on the surfaces of outdoor bronze statues, copper roofing, and other architectural copper exposed to urban atmospheres. It forms a large part of the green patina on the Statue of Liberty.

For collectors the finest crystallised specimens from localities such as Milpillas in Mexico and the Laurion district of Greece are genuinely beautiful; for mineralogists brochantite is notable as one of the most stable secondary copper sulphate minerals and the one most commonly responsible for the green colour of copper-bearing oxidised zones in humid environments.

It forms short prismatic to acicular crystals, often striated lengthwise, in brilliant emerald-green with a vitreous lustre, either as isolated crystals or in radiating groups, druses, and dense fibrous crusts.

It may form pseudomorphs after malachite, azurite, and langite, and can itself be replaced by chrysocolla. Acicular brochantite has occasionally been confused with acicular dioptase in old collections.

Brochantite forms in the oxidised zones of copper sulphide deposits where sulphate-bearing oxidising groundwater contacts copper-bearing minerals. Its relative stability compared to malachite and azurite means it tends to persist further from the primary sulphide zone and is often the last secondary copper mineral to form before complete oxidation to chrysocolla and iron hydroxides.

 


Uses and History

Brochantite has no industrial applications. It is one of the most commonly collected secondary copper minerals, with well-crystallised specimens from fine localities being highly sought.

It was first described in 1824 by the French mineralogist Serve-Dieu Abailard “Armand” Lévy, who named it in honour of André Jean François Marie Brochant de Villiers (1772-1840), Professor at the École des Mines in Paris, distinguished French geologist and cartographer, and the director of France’s first geological map.

The finest collector specimens come from the Milpillas Mine near Cananea in Sonora, Mexico, which has produced large, brilliantly lustred crystals considered among the finest of species; Bisbee in Cochise County, Arizona, USA; the Laurion (Lavrion) district in Attica, Greece, particularly the Jean Baptiste and Kamariza mines; and the Cerro Colorado Mine in the Tarapacá Region of Chile.

 


Mineralogy

Chemistry
A copper sulphate hydroxide with the formula Cu4SO4(OH)6.
Colours and Variations
Emerald-green to dark green; occasionally greenish-black; bluish-green in transmitted light.
Streak
Pale green
Lustre
Vitreous
Transparency
Transparent to translucent
Fracture
Conchoidal to irregular; perfect cleavage in one direction
Tenacity
Brittle
Crystal habit
Short prismatic to acicular, striated lengthwise; radiating groups; druses; dense fibrous crusts; pseudomorphs after malachite and azurite known
Mohs hardness
3.5 – 4.0
Fluorescence
Non-fluorescent
Specific Gravity
3.97
Easiest testing method
The brilliant emerald-green prismatic to acicular crystals with vitreous lustre, combined with high specific gravity for a green mineral and the secondary copper deposit context, are characteristic of brochantite. It is distinguished from malachite by crystal habit (malachite is typically botryoidal or fibrous rather than truly prismatic) and by not effervescing in acid (brochantite is a sulphate, not a carbonate). From antlerite (closely related and similar) by X-ray diffraction only. The green patina on outdoor bronze statues is predominantly brochantite.

Hazards and Warnings

Toxic mineral: contains copper. Copper compounds are toxic. Mineral collectors should wash their hands after handling specimens and avoid any contact with the mouth or inhalation of dust.

Almost all rocks, minerals (and, frankly, almost all other substances on earth) can produce toxic dust when cutting, which can cause serious respiratory conditions including silicosis. When cutting or polishing rocks, minerals, shells, etc, all work should be done wet to minimise the dust, and a suitable respirator or extraction system should be used.

 


Translations

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  • Брошантит

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  • Brochantite

Japanese:

  • ブロシャン石

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Further Reading / External Links