If you’re a regular on mineral identification or discussion forums or groups, you’ll have seen posts with photos of an unusual material, followed by a dozen comments of “SLAG!”.

It’s not an insult, honest*. Fans of mineral identification and those who give their time to attempt it are probably a bit sick of slag by now but it occurs in so many forms that it can be quite tricky to identify.

 

Big update for 2024: I’d like to thank Michael Kelley from Durham University for providing a huge amount of beach material and slag for me to process and photograph; the resulting images are now on this page.

 

Even more annoyingly, it looks similar to volcanic rocks like scoria due to its vesicular nature. Glassy or highly vitrified types of slag have been confused with Obsidian many, many times. It has even been used to imitate meteorites. 

 

*If you’re an international reader, Slag has another, more adult meaning in the UK. If you’re a UK based reader, stop giggling. 

So… what is it, where does it come from, where is it found, and what types are there?

The term slag isn’t really accurate, to start with. In online groups and discussion forums, we tend to use the term ‘slag’ to refer to all industrial byproducts that might get confused with minerals or rocks.

However, ‘Slag’ specifically refers to byproducts created during metal smelting. It is often a mixture of silicon dioxide and other metal oxides or metal sulfides; the exact composition depends on both the method used for smelting and the compositions of the ore being smelted.

It is genuinely quite difficult to distinguish between certain materials, though – so ‘slag’ is used to describe them to a reasonably satisfactory standard, at least for beginners. A more general term might be ‘clinker’, but I’m not sure if that is a UK colloquialism or not. As such, I’ll use the term slag/clinker interchangeably or together, as I’m not planning on writing too much about metal smelting any time soon…

 

Typically the materials are grey, brown, or black – sometimes with an iridescent effect. They often have some rough or sharp surfaces, possibly some ‘glassy’ looking surfaces, and usually a number of bubbles (vesicles) or bubble marks. They may or may not be attracted to a magnet, and they may or may not be picked up by a metal detector.

 

I am writing this from a UK perspective, which may not hold true across most of the world (but likely does). That is, slag or clinker is everywhere. In the UK, this commonly takes the form of iron smelting slag.

It was used to build up railway embankments and tracks, to cover footpaths, to provide shoring up, hardcore, etc – sometimes it is mixed with mud, concrete, and other debris to form cheap hardcore. My house is built on the road between a major city and numerous small collieries; my garden is full of clinker and slag!

 

Any old industrial land in the UK will have some, somewhere. Most old paths will have some, somewhere. The canals, the railways, industrial areas – honestly, it is everywhere. It is sometimes even found on top of hills or mountains, at the sites of old mines or smelting plants. The rest of the world is likely the same, at least in the areas with heavy coal or iron producing industrial histories.

Some slag is ancient; there is significant archaeological evidence of Copper smelting slag at various sites from the Bronze Age. The slag there can be chemically analysed and potentially help to determine what minerals were being smelted, and where from. There is a photograph above of a large piece of Iron smelting slag from the Scandinavian Iron age.

 

So what’s the difference between ‘slag’ and ‘slag glass’?!

One of the more confusing uses of this name comes into play when we consider three different names – ‘glassy slag’, ‘glass slag’, and ‘slag glass’. Surprisingly, only the first two mean the same thing.

Glassy slag is just… slag, with glassy attributes. It is high in silica, often has shiny or polished looking sides, high heat from whatever industrial process it comes from has formed glass, essentially.

To confuse matters, there is a type of glass referred to as ‘slag glass’, or ‘malachite glass’, which was possibly originally made with glass and slag and press formed.

To… yep, you got it – confuse matters even more – many people refer to any large pieces of waste glass as ‘glass slag’, meaning it is ‘an industrial byproduct made of glass’. This includes things like cullet glass – large chunks of which are often mistaken for minerals or crystals. It makes sense to me, especially if there are numerous layers, colours etc of waste glass!

 

To sum up, the common usage of the word ‘slag’ in collecting groups etc now seems to refer to ‘an industrial byproduct’ rather than the strictly accurate metallurgical definition. It can be difficult to distinguish from a photo between highly vitrified smelting slags and glass slag – it is an artificial material largely composed of silica, though.

While this isn’t strictly an accurate use of the word, language evolves and in this case, it is accurate enough for most. It’s either that or we all start saying ‘glass byproduct’, which just doesn’t have the same ring to it. For archaeologists I think the issue is a little more in-depth; for mineral collectors who aren’t specifically interested in historical slag, hopefully the one term will be enough.

Pieces of seemingly vitreous slag, which turns out not to be – with the colour coming from smelting of various metals. I believe blue colouration is typically due to iron refining.

These pieces come from the area around Seaham.

The same material, broken up with a rock hammer. Please note, it is not glassy inside. The polished surface is due to the abrasive action of sea and sand.

These pieces are a vitreous material; the dark pieces may be a result of smelting, or some other industrial process consisting of considerable heat.

The other glassy pieces in a pale blue colour are a true glass, with a great number of bubbles inside. These may be a remnant of local glassmaking.

These darker pieces are the most common forms of slag to be found in the UK. They were used as hardcore along railway lines, under roads, hell – I have found some on a mountain path hundreds of metres above sea level. Half the country is built on top of the stuff.

They are often glassy, and have ‘vesicles’ (bubbles). Potentially easy to confuse with lava, Obsidian, or meteorites.