Chenevixite

A secondary copper-iron arsenate mineral, typically found around other arsenate and carbonate copper minerals.

Mostly of interest to micromount specimen collectors.

Toxic mineral: contains arsenic. 

Information about Chenevixite

Chenevixite is a secondary copper iron arsenate hydroxide mineral forming in the oxidised zones of polymetallic ore deposits.

Its naming history is remarkable for its irony: the mineral was named after Richard Chenevix, an Irish-born chemist who explicitly and publicly objected to the practice of naming minerals after people – a position he set out in his 1811 work Observations on Mineralogical Systems – yet a mineral was named for him anyway, presumably because the analytical work he published in 1801 on a Cornish arsenate of copper and iron had been the first scientific description of what was later recognised as the mineral bearing his name.

Chenevixite typically forms as olive-green to dark green to yellowish-green compact masses, crusts, and botryoidal aggregates, rarely as tiny prismatic crystals visible under magnification.

It is the Fe3+-dominant member of the chenevixite-luetheite series, in which aluminium substitutes for iron to produce luetheite. It belongs to the same secondary arsenate family as olivenite, cornwallite, and strashimirite – all sharing the copper-arsenic-hydroxide chemistry and the oxidised zone origin – and is a relatively inconspicuous member of that family without the striking colours of olivenite or the unusual habits of strashimirite.

 


Uses and History

Chenevixite has no industrial applications. It is collected as a scientific specimen.

Richard Chenevix (c. 1774, Ballycommon, Co. Offaly, Ireland – 5 April 1830, Paris) was a chemist and playwright who worked primarily in France and England. In 1801 he published in the Philosophical Transactions of the Royal Society a detailed analysis of arsenates of copper and iron from Cornwall, which later proved to describe chenevixite.

His 1811 Observations on Mineralogical Systems opposed the naming of minerals after people, arguing that descriptive or chemical names were more useful. The mineral was formally described and named chenevixite by F. Pisani in 1866, from Cornish material, apparently in deliberate commemoration of the very man who had argued against such commemorations. No record survives of whether Pisani intended this as a tribute, an irony, or simply a straightforward acknowledgement of Chenevix’s foundational analytical work.

The finest collector specimens come from the Clara Mine at Oberwolfach in Baden-Württemberg, Germany, which produces the most photographed material; the Christiana and related mines at Laurion (Lavrion), Attica, Greece; and from Cornwall, England, including the type material region. The mineral also occurs at Arizona porphyry copper deposits, as documented in the crystal structure paper by Burns, Smith, and Steele (2000) in Mineralogical Magazine.

 


Mineralogy

Chemistry
A copper iron arsenate hydroxide with the formula Cu2Fe2(AsO4)2(OH)4. Monoclinic. Secondary arsenate in oxidised copper-arsenic ore deposits.
Colours and Variations
Olive-green to dark green, yellowish-green, or occasionally dark greenish-brown.
Streak
Pale green to yellowish-green
Lustre
Waxy to resinous; dull in fine-grained masses
Transparency
Translucent to opaque
Fracture
Subconchoidal to irregular
Tenacity
Brittle
Crystal habit
Compact masses and crusts; botryoidal aggregates; tiny prismatic crystals visible under magnification only
Mohs hardness
3.5 – 4.0
Fluorescence
Non-fluorescent
Specific Gravity
4.38 – 4.40
Easiest testing method
Olive-green compact masses in a copper-arsenic oxidised ore setting with notably high specific gravity for their dull appearance is the most useful field indicator. Chenevixite is not reliably distinguished from other olive-green secondary copper arsenates (cornwallite, olivenite massive forms) in hand specimen. X-ray diffraction and electron microprobe analysis to confirm Fe vs Al dominance are required for definitive identification from luetheite.

Hazards and Warnings

Highly toxic mineral: contains copper and arsenic. Arsenic compounds are highly toxic. Mineral collectors must wash their hands thoroughly after handling specimens, must not inhale any dust, and must keep specimens away from children.

Almost all rocks, minerals (and, frankly, almost all other substances on earth) can produce toxic dust when cutting, which can cause serious respiratory conditions including silicosis. When cutting or polishing rocks, minerals, shells, etc, all work should be done wet to minimise the dust, and a suitable respirator or extraction system should be used.

 


Translations

Arabic:

Hindi:

Portuguese:

  • Chenevixita

Bengali:

Indonesian:

Punjabi:

English:

  • Chenevixite

Italian:

  • Chenevixite

Russian:

French:

  • Chénevixite

Japanese:

Spanish:

  • Chenevixita

German:

  • Chenevixít

Korean:

Thai:

Gujurati:

Mandarin Chinese:

Urdu:

 


Further Reading / External Links